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Members of the nation's largest union of postdoctoral scientists overwhelmingly ratified its first-ever contract Wednesday with the University of California, which was tentatively agreed to last month. The contract between the Postdoctoral Researchers Organize/United Auto Workers union and the university will tie the researchers' annual compensation to the federal government's pay scale for postdocs at the National Institutes of Health and promise annual increases of between 1.5 percent and 3 percent, depending on the size of their stipends, between 2010 and 2015. The contract could also require postdocs to make some contributions to their health premiums in 2012 and beyond. The union, which represents an estimated 10 percent of the postdoctoral researchers in the United States, struggled to win recognition but ultimately did so in 2008.